Oligomeric carbonate chainstoppers
US4994594A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Feb 29, 1988 |
| Grant date | Feb 19, 1991 |
| Priority date | — |
| Expiry date | Feb 29, 2008 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08G64/14
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Oligomeric carbonate dihydroxyaromatic-based chainstoppers are disclosed. One example of this type of chainstopper is a bisphenol A bischloroformate oligomer monocapped with phenol. These chainstoppers may be prepared by phosgenating a dihydroxyaromatic compound to terminate one or both of the terminal oxygen atoms with chlorocarbonyl groups, followed by reaction of the chlorocarbonyl-terminated material with a phenolic-type compound in the presence of an amine catalyst. The chainstoppers of the present invention are very useful in accurately controlling the molecular weight of polycarbonates formed by various processes, while also preventing the formation of undesirable by-products, such as diarylcarbonates.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.