Patent · US Expired

Electrospray ionization interface and method for mass spectrometry

US4999493A · kind A · utility

65Cited by
5References
17Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 24, 1990
Grant dateMar 12, 1991
Priority date
Expiry dateApr 24, 2010

Classification

  • Technology area (CPC H)Electricity
  • CPC primaryH01J49/0486
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

Improved techniques are provided for forming ionized molecules from electrosprayed droplets for analysis by a mass spectrometer. A high voltage is applied to a capillary tube for spraying droplets at substantially atmospheric pressure or above, and the electrosprayed droplets contain sample solute of interest and solvent. The electrosprayed droplets are passed into an ion generating chamber which is maintained at a pressure in the range of from 0.2 Torr to 10 Torr. The walls of the ion generating chamber are controllably heated to a temperature which will desolvate the droplets and produce ionized molecules of interest for analysis by the mass spectrometer. The electrospray technique does not rely upon a countercurrent heated gas flow, and provides a particularly simple and inexpensive means to couple electrospray ionization to either quadrupole or magnetic mass analyzers.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.