Patent · US Expired

Terminal perfluoroalkylsilane compounds

US5011963A · kind A · utility

48Cited by
5References
4Claims
0Family size

Assignees

Inventors

Key dates

Filing dateFeb 9, 1989
Grant dateApr 30, 1991
Priority date
Expiry dateFeb 9, 2009

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07F7/1804
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A terminal perfluoroalkylsilane compound F(CF.sub.2).sub.m (CH.sub.2).sub.n Si(CH.sub.3).sub.p X.sub.3-p (m+n=10 to 32 carbon atoms in fluoroalkyl group) is prepared by a hydrosilylation reaction of a terminal perfluoroalkene compounds F(CF.sub.2).sub.m (CH.sub.2).sub.1+q CH.dbd.CH.sub.2 (1+q+2=n) with the hydrodiensilane HSi(CH.sub.3).sub.p X.sup.3.sub.3-p. The F(CF.sub.2).sub.m (CH.sub.2).sub.1+q CH.dbd.CH.sub.2 are synthesized by a Grignard's reaction of a Grignard's reagent X.sup.2 Mg(CH.sub.2).sub.q CH.dbd.CH.sub.2 obtained from a terminal alkenyl halogen compound X.sup.2 (CH.sub.2).sub.q CH.dbd.CH.sub.2 with a terminal fluoroalkyl halogen compound F(CF.sub.2).sub.m (CH.sub.2).sub.1 X.sup.1. The terminal perfluoroalkylsilane compound has a sufficient lubricating effect and is useful for a coating agent with long and continuous lubricity.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.