Patent · US Expired

Metal electrodes for electrochemical processes

US5017276A · kind A · utility

3Cited by
2References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 26, 1989
Grant dateMay 21, 1991
Priority date
Expiry dateDec 26, 2009

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC25B11/093
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

Metal electrodes provided with a coating consisting essentially of a mixed oxide compound of (i) a compound of the general formula ABO.sub.4, having a structure of the rutile-type, where A is an element in the trivalent state selected from the group consisting of Al, Rh and Cr, and B is an element in the pentavalent state selected from the group consisting of Sb and Ta, (ii) RuO.sub.2 and (iii) TiO.sub.2 ; wherein the mole fraction of ABO.sub.4 is between 0.01 and 0.42, the mole fraction of RuO.sub.2 is between 0.03 and 0.42, and the mole fraction of TiO.sub.2 is between 0.55 and 0.96. The electrodes have low precious metal content, provide improved durability and improved current efficiency-anodic overvoltage performance. They are used in the electrolysis of chloride containing liquors in the production of, for example, chlorine and more particularly, chlorate.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.