Betaine group-containing derivatives of carboxymethylcellulose, their synthesis and their use in cosmetic preparations

US5023246A · kind A · utility

Assignee

• Th. Goldschmidt. AG · DE

Inventors

• Burghard Gruning · Essen, DE
• Klaus Hoffmann · Essen, DE
• Gotz Koerner · Essen, DE
• Hans-Joachim Kollmeier · Essen, DE

Key dates

• Filing date: May 17, 1989
• Grant date: Jun 11, 1991
• Expiry date: May 17, 2009

Classification

• Technology area (CPC A): Human Necessities
• CPC primary: A61K2800/5428
• WIPO field: Pharmaceuticals
• WIPO sector: Chemistry

Abstract

Betain group-containing derivatives of carboxymethylcellulose are disclosed. They are characterized in that all or a portion of the carboxymethyl groups are or is replaced by groups of the general formula ##STR1## wherein R.sup.1 is hydrogen or methyl group, PA0 R.sup.2 is a divalent aliphatic hydrocarbon group with 2 to 5 carbon atoms, PA0 R.sup.3, R.sup.4 is an alkyl group with 1 to 4 carbon atoms, PA0 R.sup.5 is a divalent aliphatic hydrocarbon group with 1 to 10 carbon atoms, with the proviso that, on the average, at least 0.1 betaine groups are contained for each anhydroglucose unit of the polymeric molecule. Also, a method for the synthesis of these compounds and their use in cosmetic preparations, especially for the care of hair, are disclosed. In addition, novel derivatives of carboxymethylcellulose with tertiary amino groups are taught as intermediates. In these derivatives, all or a portion of these groups are or is replaced by groups of the general formula ##STR2## in which the substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meaning, with the proviso that, on the average, at least 0.1 tertiary amino groups are contained per anhydroglucose unit of the po…