Patent · US Expired

Process for the preparation of cumene

US5055627A · kind A · utility

72Cited by
22References
8Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 11, 1989
Grant dateOct 8, 1991
Priority date
Expiry dateSep 11, 2009

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/10
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

Cumene is produced in a catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 50.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic by feeding propylene to the catalyst bed while benzene is conveniently added through the reflux to result in a molar excess present in the reactor to that required to react with propylene, thereby reacting substantially all of the propylene and recovering benzene as the principal overhead and cumene and diisopropyl benzene in the bottoms. The bottoms are fractionated, the cumene recovered and the bottoms are contacted with benzene in the liquid phase in a fixed bed straight pass reactor under conditions to transalkylate the benzene thereby converting most of the diisopropyl benzene to cumene which is again separated and recovered.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.