Patent · US Expired

Anionic initiator system for polymerizing monomers

US5063190A · kind A · utility

15Cited by
14References
4Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 19, 1990
Grant dateNov 5, 1991
Priority date
Expiry dateJun 19, 2010

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F36/04
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Liquid telechelic polymers are made from dienes and are produced via anionic polymerization. While having low molecular weight, for example less than 15,000, the telechelic polymers are generally gel-free, have high amounts of trans-1,4 structure, low vinyl unsaturation and low bulk viscosities. The liquid telechelic polymers are made utilizing a trimetallic initiator comprised of (1) an organopolylithium compound and (2) a complex of a trialiphatic substituted aluminum compound or derivative thereof and a barium salt of an organic alcohol.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.