Patent · US Expired

Gas-phase alpha-olefin polymerization process in the presence of an activity retarder

US5066736A · kind A · utility

40Cited by
4References
14Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 5, 1989
Grant dateNov 19, 1991
Priority date
Expiry dateSep 5, 2009

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/901
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A process for the continuous polymerization of one or more alpha-olefins with a transition metal catalyst, in a reactor having a fluidized and/or mechanically stirred bed, in which a very small amount of an activity retarder, generally less than 0.1 ppm, is introduced continuously into the reactor at a flow rate which is varied with time so as to keep substantially constant either the polymerization rate or the content of transition metal in the polymer produced. Suitable activity retarders include polymerization inhibitors such as, for example, oxygen, alcohols, carbon monoxide and carbon dioxide and electron donor compounds such as amides and ethers.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.