Patent · US Expired

Molten salt electrolysis with non-consumable anode

US5069771A · kind A · utility

19Cited by
7References
13Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 28, 1989
Grant dateDec 3, 1991
Priority date
Expiry dateApr 28, 2009

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC25C7/025
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

A method of electrowinning a metal by electrolysis of a melt containing a dissolved species of the metal to be won using a non-consumable anode having a metal, alloy or cermet substrate and an operative anode surface which is a protective surface coating of cerium oxyfluoride preserved by maintaining in the melt a suitable concentration of cerium, is characterized by using an anode provided with an electronically conductive oxygen barrier on the surface of the metal, alloy or cermet substrate. The barrier layer may be a chromium oxide film on a chromium-containing alloy substrate. Preferably the barrier layer carries a ceramic oxide layer, e.g. of stabilized copper oxide which acts as anchorage for the cerium oxyfluoride.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.