Process for preparing a vanadium-based catalyst suitable for olefin polymerization
US5070054A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Aug 2, 1990 |
| Grant date | Dec 3, 1991 |
| Priority date | — |
| Expiry date | Aug 2, 2010 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S526/904
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The present invention relates to a process for preparing a Ziegler-Natta type catalyst based on a vanadium compound precipitated on a MgCl.sub.2 spherical support. The catalyst preparation consists of contacting within a liquid hydrocarbon a vanadium-reducing agent chosen from organometallic compounds with a vanadium compound soluble in the liquid hydrocarbon containing at least one halogen and one alkoxy group, and with a support containing (i) MgCl.sub.2 free from Mg-C bond and (ii) an organic electron donor compound free from labile hydrogen. The support consists of spherical particles having a well-defined diameter and a narrow particle size distribution. The catalyst is particularly suitable for manufacturing in a gas phase process elastomeric copolymers of propylene.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.