Black surface layer on light metal

US5075178A · kind A · utility

Assignee

• Jenoptik Jena GmbH · DE

Inventors

• Juergen Schmidt · Goldkronach, DE
• Thomas Furche · Jena, DE
• Roland Erdmann · Jena, DE
• Marion Reichert · Jena, DE

Key dates

• Filing date: Jan 7, 1990
• Grant date: Dec 24, 1991
• Expiry date: Jan 7, 2010

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y10T428/12812
• WIPO field: Surface technology, coating
• WIPO sector: Chemistry

Abstract

The invention relates to a cyanide-free electrolyte being harmless to the environment and to health which makes feasible the production of black surface layers on light metals or on alloys of the latter, preferably titanium, remaining deeply-black and adhesive even after extreme changes in the ambient temperature and having nearly equal values of the optical absorptivity of radiation and of the thermal emission capability (the .alpha./.epsilon.-ratio is about 0.95) by means of the anodic oxidation by spark discharge (ANDF-method). These layers are absolutely X-amorphous and show, hence, an ideal optically isotropic behavior regarding the reflection of radiation. Due to their minmum evolution of gases they offer a high thermovacuum stability. The electrolyte consists of an ammoniacal solution of K.sub.2 H.sub.2 PO.sub.4 potassium dihydrogenphosphate and K.sub.2 CrO.sub.4 potassium chromate. The homogeneity of the optically black layers is ensured by not using fluoride ions and employing acetate ions. Such layers comprise titanium, chromium and copper in ratios of Cr:Ti=1: (1.9 to 2.2) and Cr:Cu=1:(0.8 to 1.3).