Preparation of hexene-1,6-dioic acids
US5077433A · kind A · utility
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18Claims
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Key dates
| Filing date | Apr 30, 1990 |
| Grant date | Dec 31, 1991 |
| Priority date | — |
| Expiry date | Apr 30, 2010 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C51/12
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The hexene-1,6-dioic acids, e.g., hex-3-ene-1,6-dioic acid, are prepared by reacting carbon monoxide and water with at least one diacyloxylated butene, in the presence of a catalytically effective amount of palladium and at least one quaternary onium chloride of one of the Group VB elements nitrogen or phosphorus, such element being tetracoordinated via carbon atoms and with the proviso that such nitrogen atom may be coordinated to two pentavalent phosphorus atoms.
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