Patent · US Expired

Catalytic hydrogenation process

US5093535A · kind A · utility

70Cited by
6References
23Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 4, 1990
Grant dateMar 3, 1992
Priority date
Expiry dateJun 4, 2010

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J2208/0061
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A liquid phase catalytic hydrogenation process is described in which an organic feedstock, such as an aldehyde containing from 2 to about 20 carbon atoms, is contracted with hydrogen in the presence of a solid hydrogenation catalyst under hydrogenation conditions to produce a hydrogenation product, such as the corresponding alcohol containing from 2 to about 20 carbon atoms, which process comprises passing a feed solution of the organic feedstock in an inert diluent therefor downwardly in co-current with a hydrogen-containing gas through a hydrogenation zone containing a bed of a particulate hydrogenation catalyst whose particles substantially all lie in the range of from about 1.5 mm to about 5 mm, maintaining the bed of catalyst particles under temperature and pressure conditions conducive to hydrogenation, recovering from a bottom part of the bed a liquid phase containing the hydrogenation product, controlling the rate of supply of the feed solution to the bed so as to maintain a superficial liquid velocity of the liquid down the bed in the range of from about 1.5 cm/sec to about 5 cm/sec, and controlling the rate of supply of the hydrogen-containing gas to the bed so as to main…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.