Patent · US Expired

Catalytic reaction of propyelne with tertiary butyl hydroperoxide

US5107067A · kind A · utility

3Cited by
9References
11Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 12, 1989
Grant dateApr 21, 1992
Priority date
Expiry dateMay 12, 2009

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J2531/96
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

Complexes made by reacting an ammonium-containing molybdenum compound with an alkylene glycol in the presence of water at an elevated temperature are described. Mild stripping of the water subsequent to complex formation is preferred. If some of the water is left in the complex, it may serve as an excellent olefin epoxidation catalyst. The ratio of moles of alkylene glycol to gram atoms of molybdenum in the complex forming reaction ranges from 7:1 to 20:1. Ethylene glycol and propylene glycol are the particularly preferred alkylene glycols.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.