Patent · US Expired

Process for the production of polyarylene sulfides with lithium halide and alkali metal hydrosulfide

US5109110A · kind A · utility

7Cited by
12References
6Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 12, 1989
Grant dateApr 28, 1992
Priority date
Expiry dateJun 12, 2009

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G75/0259
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Polyarylene sulfides are produced by polymerizing a dihalogen aromatic compound with an alkali metal hydrosulfide in the presence of a lithium halide in an organic polar solvent. In this polymerization, an alkali metal hydroxide and/or carbonate is added and a branching agent such as a trihalogen aromatic compound or a halogen aromatic nitro compound is used, if desired. The polyarylene sulfides have a high molecular weight and a less salt contents and a high degree of whiteness.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.