Patent · US Expired

Removal of AOX FRM bleach plant mill effluents by pH shift using the alkalinity/acidity sources available at the mill

US5120448A · kind A · utility

16Cited by
6References
15Claims
0Family size

Inventors

Key dates

Filing dateSep 19, 1990
Grant dateJun 9, 1992
Priority date
Expiry dateSep 19, 2010

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S210/928
  • WIPO fieldEnvironmental technology
  • WIPO sectorChemistry

Abstract

A process for removal of adsorbable organic chlorine (AOX) in which the acid-soluble AOX present in kraft chlorination (C.sub.D) effluents are destablized and converted to inorganic chloride by pH shift using the alkalinity and acidity sources available at the mill; C.sub.D effluent, typically having a pH of 1-2 and E.sub.1 effluent, typically having a pH of 9-12 can be mixed in various proportions to achieve a pH between 6.5-9.0 or the C.sub.D effluent is adjusted in pH to 6-11 with an alkaline composition so taht alkaline hydrolysis as well as precipitation of organic material occurs and the treated effluent contains less AOX than present in the original untreated effluents; the AOX removal is enhanced substantially by (i) the presence of a sulphide or (ii) by carrying out the alkaline treatment at elevated temperature and pressure.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.