Patent · US Expired

Process for opening cyclopropane rings

US5126461A · kind A · utility

1Cited by
0References
8Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 14, 1990
Grant dateJun 30, 1992
Priority date
Expiry dateNov 14, 2010

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C2602/08
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Process for ring opening compounds of the formula ##STR1## in which R.sup.1 is heteroaryl or aryl, R.sup.2 is a leaving group, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently selected from hydrogen, alkyl, aralkyl, aryl, heteroaryl and alkenyl, provided that at least one of the groups R.sup.3 to R.sup.6 is other than hydrogen, by breaking the bond joining the carbon atom attached to R.sup.3 and the carbon atom attached to R.sup.6 in organic solution using silica, giving useful diene or allyl derivatives, certain of which are novel.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.