High char yield silazane derived preceramic polymers and cured compositions thereof
US5136007A · kind A · utility
Assignee
Inventor
Key dates
| Filing date | Dec 8, 1989 |
| Grant date | Aug 4, 1992 |
| Priority date | — |
| Expiry date | Dec 8, 2009 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08G77/54
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Novel polysiloxane-silazane preceramic polymer compositions are prepared by the controlled hydrolysis polymerization of a trimer or tetramer of a monomer of the structure ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently alkyl groups containing from 1 to 4 carbon atoms, R.sup.a, R.sup.b, R.sup.c, and R.sup.d are independently alkenyl or alkyl groups containing from 2 to 6 carbon atoms with the proviso that at least one of R.sup.a, R.sup.b, R.sup.c, or R.sup.d group is an alkenyl group. The polysiloxane-silazane polymers are cured by heat and optionally free radical initiators such as various peroxides. The cured preceramic polymers so formed can be u sed in the pyrolyzed or non-pyrolyzed state as adhesives, coatings, binders, fibers, matrix resins, and the like.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.