Patent · US Expired

Process for the production of gamma butyrolactone THF in predetermined amounts

US5149836A · kind A · utility

9Cited by
10References
4Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 25, 1991
Grant dateSep 22, 1992
Priority date
Expiry dateJul 25, 2011

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07D307/08
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

This invention provides a vapor phase process for the production of gamma-butyrolactone and tetrahydrofuran in a predetermined ratio by the steps of: hydrogenating a vapor mixture of maleic anhydride and excess hydrogen over a first bed of a Cu-Zn-Al catalyst, and directly contacting the crude reactor effluent therefrom with hydrogen over a second bed of Cu-Zn-Cr catalyst during a predetermined contact time and at a defined temperature, using selected amounts of catalyst in each bed.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.