Process for the separation of tert. butyl ethyl ether from mixtures
US5158652A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Apr 9, 1991 |
| Grant date | Oct 27, 1992 |
| Priority date | — |
| Expiry date | Apr 9, 2011 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S203/06
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
For the separation of tert. butyl ethyl ether from mixtures with ethanol, there are provided two distillation stages, the first being carried out at a pressure p.sub.1 equal to or higher than 1 bar, the second at a pressure p.sub.2 below p.sub.1 by a value .DELTA.p or 0.5 to 12 bars, p.sub.2 then being 0.5 to 10 bars. The second column distillate is partly supplied as reflux to the head of the second column and is in part recycled to the head of the first column. The purified TBEE is collected at the bottom of the first column and the purified ethanol at the bottom of the second column. This separation process can be integrated into a TBEE production unit comprising etherification by ethanol of the isobutylene contained in a C.sub.4 fraction from a catalytic cracking or steam cracking stage. The ethanol separated from the TBEE is then recycled to the etherification zone.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.