Patent · US Expired

Rigid-rod benzobisazole copolymer containing cyclic phosphate ester

US5175232A · kind A · utility

2Cited by
6References
11Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 22, 1992
Grant dateDec 29, 1992
Priority date
Expiry dateMay 22, 2012

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G75/32
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Rigid-rod aromatic heterocyclic copolymers having repeating units of the formula: ##STR1## wherein n has a value of about 0.10 to 0.99, m is 1.0-n, Ar is a para-ordered divalent aromatic moiety, as defined hereinafter, and wherein Ba is a benzobisazole moiety of the formula: ##STR2## wherein X is --O--, --S-- or --NH. Ar can be any para-ordered divalent moiety such as, for example, 1,4-phenylene, 4,4'-biphenylene, 4,4"-terphenylene, and the like, as well as substituted divalent moieties, such as, for example: ##STR3## wherein R is Q or an alkyl group having 1 to 4 carbon atoms, wherein Q is ##STR4## wherein Z is --O-- or --S--; ##STR5## wherein R is as defined above, or ##STR6## wherein R.sup.1 and R.sup.3 are --H or -phenyl, R.sup.2 is --H or ##STR7## wherein Q is as defined above, and R.sup.4 is R.sup.2 or ##STR8##

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.