Process for separating para-xylene from a C.sub.8 and C.sub.9 aromatic mixture
US5177295A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Dec 23, 1991 |
| Grant date | Jan 5, 1993 |
| Priority date | — |
| Expiry date | Dec 23, 2011 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C7/13
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
In the process flow scheme for chromatographically separating para-xylene from C.sub.8 isomers containing substantial amounts of C.sub.9 aromatic hydrocarbon impurities with BaX or KY zeolite adsorbent and heavy desorbents, e.g., tetralin and diethyltoluene, a bottoms stream from the extract fractionation column containing desorbent is recycled to the separation unit and a sidecut stream, containing C.sub.9 aromatic hydrocarbon impurities and a minor amount of the desorbent from the raffinate stream, is directed to the raffinate fractionation column, thereby removing C.sub.9 aromatic hydrocarbons from the desorbent before recycling the desorbent to the separation unit, and preventing C.sub.9 aromatics from building up in the desorbent input. A fractionator for the extract column bottoms stream is eliminated, lowering capital costs, and energy requirements for the raffinate column are reduced.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.