High density lithium-based ceramics from zeolites
US5179051A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Dec 16, 1991 |
| Grant date | Jan 12, 1993 |
| Priority date | — |
| Expiry date | Dec 16, 2011 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/258
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
This invention relates to a process for preparing a lithium containing ceramic article. The process provides a ceramic article that is substantially crack free and has as its principal crystalline phase a beta-eucryptite phase, a beta-spodumene phase, or a mixture thereof. The process comprises calcining a powder of a lithium-exchanged zeolite up to its collapse temperature for a time sufficient to collapse the zeolite framework and provide an amorphous powder. The amorphous powder is now formed into a shaped article and sintered at a temperature of about 700.degree. to about 1150.degree. C. for a time of about 1 to about 12 hours. The zeolites which can be used are those having a SiO.sub.2 Al.sub.2 O.sub.3 ratio of about 2 to about 8.5 and include zeolite B, zeolite ZK-19, zeolite W, phillipsite, hormotome, gismondine and mixtures thereof and have a sodium content less than about 1 weight percent. It is preferred that the lithium-exchanged zeolite have an average particle size of less than about 10 microns.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.