Patent · US Expired

4-(N-benzyl-N-methylamino)pyridine acid salts and use in preparation of polymer-supported catalysts

US5183895A · kind A · utility

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14Claims
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Assignee

Inventors

Key dates

Filing dateFeb 18, 1992
Grant dateFeb 2, 1993
Priority date
Expiry dateFeb 18, 2012

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07D213/74
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A cross-linked polymer-supported 4-(N-benzyl-N-methylamino) pyridine material and process for its preparation in high yield and having effective physical and catalytic properties. The polymer supported catalyst is characterized by the suspension copolymerization of an organic phase containing the corresponding vinyl-substituted pyridine monomer, a styrene monomer, and a suitable cross-linking agent and free radical-generating catalyst in the presence of an aqueous phase containing a cellulose ether derivative as the stabilizing agent. A purified acid salt of the vinyl-substituted pyridine monomer useful in polymerizations and stable for storage as either a solid or an aqueous solution.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.