Patent · US Expired

Reactor for exothermic reactions

US5190730A · kind A · utility

13Cited by
27References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 8, 1991
Grant dateMar 2, 1993
Priority date
Expiry dateJul 8, 2011

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J2208/00539
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A liquid phase process for oligomerization of C.sub.4 and C.sub.5 isoolefins or the etherification thereof with C.sub.1 to C.sub.6 alcohols wherein the reactants are contacted in a reactor with a fixed bed acid cation exchange resin catalyst at an LHSV of 5 to 20, pressure of 0 to 400 psig and temperature of 120.degree. to 300.degree. F. Wherein the improvement is the operation of the reactor at a pressure to maintain the reaction mixture at its boiling point whereby at least a portion but less than all of the reaction mixture is vaporized. By operating at the boiling point and allowing a portion of the reaction mixture to vaporize, the exothermic heat of reaction is dissipated by the formation of more boil up and the temperature in the reactor is controlled.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.