Patent · US Expired

Two-phase process for preparing poly(vinyl alcohol)-co-poly(vinylamine)

US5194492A · kind A · utility

18Cited by
5References
9Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 2, 1992
Grant dateMar 16, 1993
Priority date
Expiry dateJan 2, 2012

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F8/12
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Vinyl acetate and an N-vinyl formamide are copolymerized to yield poly(vinyl acetate)-co-poly(N-vinyl formamide) which is base hydrolyzed to poly(vinyl alcohol)-co-poly(N-vinyl formamide). Two phase hydrolysis of particles of poly(vinyl alcohol)-co-poly(N-vinyl formamide) as a slurry in methanol yields particles of poly(vinyl alcohol)-co-poly(vinylamine). Provided is a copolymer of the following general formula ##STR1## where m is 0 to 15 mole %, PA1 n is 50 to 99 mole %, x is 0 to 30 mole %, and y is 1 to 50 mole %.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.