Patent · US Expired

Rigid contact lenses with improved oxygen permeability

US5194556A · kind A · utility

26Cited by
14References
3Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 9, 1991
Grant dateMar 16, 1993
Priority date
Expiry dateJan 9, 2011

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG02B1/043
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Hard polymers with extremely high oxygen permeability are described, which consist of the copolymerization product of 1-15% by weight of a poly(dimethylsiloxane) bearing multiple polymerizable vinyl groups and having a number-average molecular weight M.sub.n of 1000-7000, 20-50% of an oligosiloxanylalkyl (meth)acrylate, 25-50% of an at least three fluorine atoms containing vinyl-monomer, 0-30% of copolymerizable monomers, which by themselves as homo- or copolymers have a Shore-D hardness of at least 85, 1-25% of polyvinyl-crosslinking monomer of 200-1000 molecular weight, and 0-15% of a watersoluble, copolymerizable monomer. The novel polymers combine a Shore-D hardness of 70-85 with an oxygen permeability of 40-90 barrers, making them outstanding materials for the manufacture and use as rigid, gas-permeable contact lenses.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.