Patent · US Expired

Process for the recovery of antimony-based catalysts used for the fluorination of halgenated hydrocarbons

US5198199A · kind A · utility

1Cited by
3References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 29, 1992
Grant dateMar 30, 1993
Priority date
Expiry dateJan 29, 2012

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/584
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

To recover the antimony contained in a solution of use antimony-containing catalyst, emananting from units for the fluorination or chlorofluorination of halogenated hydrocarbons comprising at least two carbon atoms, the solution is concentrated to the limit of distillation of antimony trichloride, an excess of chlorine is then added to convert SbCl.sub.3 to SbCl.sub.5, and SbCl.sub.5 is distilled under reduced pressure without exceeding 120.degree. C. The recoverd antimony pentachloride is sufficiently pure to be able to be recycled directly to the fluorination reactor.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.