Process for reactivating a deactivated crystalline molecular sieve group VIII metal catalyst
US5206194A · kind A · utility
Assignee
Inventor
Key dates
| Filing date | Jun 20, 1991 |
| Grant date | Apr 27, 1993 |
| Priority date | — |
| Expiry date | Jun 20, 2011 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC10G47/16
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A reactivated catalyst having optimum activity for hydrocracking and other acid catalyzed chemical conversion processes is prepared by contacting its deactivated counterpart, which contains a crystalline molecular sieve, a Group VIII noble metal hydrogenation component and carbonaceous deposits, with a gas containing molecular oxygen, preferably air, at a temperature between 950.degree. and 1200.degree. F., preferably between about 1050.degree. and 1150.degree. F., for a time sufficient to remove at least a portion of the carbonaceous deposits. When the reactivated catalyst contains a dealuminated Y zeolite that has been ion-exchanged with both noble metal and rare earth metal cations, its activity for hydrocracking in an ammonia-deficient atmosphere can be further increased by a rejuvenation procedure in which the reactivated catalyst is contacted with an aqueous ammonia solution in which an ammonium salt has been dissolved.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.