Preparation of hydrocarbons and polymers with allylic chloride end groups Friedel-Crafts catalyst

US5212248A · kind A · utility

Assignee

• BASF SE

Inventors

• Konrad Knoll · Mannheim, DE
• Klaus Bronstert · Eisenberg (Pfalz), DE
• Dietmar Bender · Schifferstadt, DE

Key dates

• Filing date: Aug 14, 1991
• Grant date: May 18, 1993
• Expiry date: Aug 14, 2011

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08F10/10
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

Hydrocarbons and polymers thereof, of the structure (I) EQU R--C(CH.sub.3).sub.2 --CH.sub.2 --C(CH.sub.3).sub.2 --CH.sub.2 --CH.dbd.CH--CH.sub.2 --Cl (I) where R is a hydrocarbon radical, are prepared by reacting corresponding starting materials which contain chlorine bonded to tertiary carbon, of the structure EQU R--C(CH.sub.3).sub.2 --CH.sub.2 --C(CH.sub.3).sub.2 --Cl (II) with from 1 to 10 moles of butadiene in the presence of a Friedel-Crafts catalyst in a solvent which is inert to the catalyst, and the hydrocarbons or polymers thereof can be reacted in a further step of the process with a compound from the group comprising ammonia, primary or secondary amine or polyamine, amino alcohol, amino ether, hydrazine or hydrazine which is substituted up to three times.