Process for preparing cycloolefin random copolymer
US5225503A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Nov 10, 1992 |
| Grant date | Jul 6, 1993 |
| Priority date | — |
| Expiry date | Nov 10, 2012 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F210/02
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The present invention is intended for the preparation of a cycloolefin random copolymer, which is a copolymer of ethylene, cycloolefin and if necessary .alpha.-olefin, in a high yield. The process for preparing a cycloolefin random copolymer according to the invention is a process for preparing a cycloolefin random copolymer comprising repeating units derived from (i) ethylene in an amount of 40 to 97% by mol, repeating units derived from (ii) cycloolefin in an amount of 3 to 60% by mol and repeating units derived from (iii) .alpha.-olefin of 3-20 carbon atoms in an amount of 0 to 20% by mol, wherein (i) ethylene, (ii) cycloolefin and if necessary (iii) .alpha.-olefin of 3-20 carbon atoms are copolymerized in a liquid phase in the presence of a catalyst formed from (A) a soluble vanadium compound having a tertiary alkoxy group or .beta.-diketone as a ligand and (B) an organoaluminum compound represented by the formula (i-Bu) .sub.n AlCl.sub.3-n wherein n is 1.0 to 2.5.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.