Patent · US Expired

Highly pure amidoximes

US5278309A · kind A · utility

13Cited by
1References
1Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 19, 1993
Grant dateJan 11, 1994
Priority date
Expiry dateFeb 19, 2013

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07D295/088
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A pure crystalline O-(2-hydroxy-3-piperidino-1-propyl) nicotinic acid amidoxime base of the Formula (Ib) ##STR1## is disclosed characterized by a melting point of 70.degree. to 73.degree. C., giving, when dissolved in an amount of 1 to 10 ml of concentrated sulfuric acid, a yellow homogeneous solution, and showing the following spectral characteristics: PA0 IR spectrum (kBr): .gamma. --O--C.dbd.N 1642 cm.sup.-1 PA0 .sup.1 H-NMR spectrum (CDCL.sub.3, .delta. ppm): 1.48 m, (6H), CH.sub.2 -piperidine; 2.42 m, (6H), 3.times.CH.sub.2 --N; 3.36, br, (1H), CH--O; 4.08 m, (3H), 1--CH.sub.2, OH; 5.2, br, (2H), NH.sub.2 ; 7.30 m (1H), pyridine-5'; 7.92 m, 4', 8.62 m (1H), 6', 8.88 m, (1H), 2'.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.