Patent · US Expired

Crosslinked polyester amide membranes and their use for organic separations

US5290452A · kind A · utility

43Cited by
7References
3Claims
0Family size

Assignee

Inventor

Key dates

Filing dateDec 5, 1991
Grant dateMar 1, 1994
Priority date
Expiry dateDec 5, 2011

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/31725
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

The present invention is directed to a polyester/amide membrane, its preparation and its use for organic liquid separation. The polyester/amide membrane is made by reacting a dianhydride with a polyester diol in a 2:1 to 1.05:1 mole ratio to end cap the diol to produce a prepolymer which is reacted with excess thionyl chloride to convert all of the unreacted anhydride and all carboxylic acid groups to acid chloride groups. The resulting acid chloride derivative is dissolved in organic solvent and interfacially reacted with a diamine dissolved in an aqueous solvent. The excess solutions are removed and the resulting thin film membrane is dried. The membranes are useful for organic liquid separations, especially the separation of aromatic hydrocarbons from mixtures of same with non-aromatic hydrocarbons, preferably under perstraction or pervaporation conditions.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.