Patent · US Expired

Process for regenerating a deactivated rhodium hydroformylation catalyst system

US5290743A · kind A · utility

18Cited by
11References
13Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMar 22, 1993
Grant dateMar 1, 1994
Priority date
Expiry dateMar 22, 2013

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/584
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A process for regenerating a deactivated hydroformylation catalyst system that contains a rhodium hydridocarbonyl tris(trisubstituted phosphine) complex, a trisubstituted phosphine, and a diphosphinoalkane, is disclosed. The process involves oxidation of the catalyst system, removal of the phosphine oxidation products, and regeneration of the catalyst system by syngas treatment, aqueous extraction, and addition of phosphine ligands.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.