Patent · US Expired

Process for making alkylated polycyclic aromatics

US5302769A · kind A · utility

5Cited by
11References
22Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 7, 1992
Grant dateApr 12, 1994
Priority date
Expiry dateDec 7, 2012

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC10G29/205
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A polycyclic aromatic is contacted with an alkyl-substituted single ring aromatic, such as toluene, o-, m- or p-xylene or mesitylene, over a catalyst comprising a zeolite, such as zeolite beta, USY or ZSM-5 to alkylate the polycyclic aromatic. The polycyclic aromatic can be a fused polynuclear aromatic, e.g. phenanthrene, or an assembly of two or more cyclic systems, e.g. biphenyl. The polycyclic aromatic can also include carbocyclic systems such as fluorene and naphthalene or heterocyclic systems such as benzothiophene and dibenzothiophene. The polycyclic aromatic can be derived from a cycle oil, coker gas oil, extract of lubricant solvent refining or crude distillate fraction. The transalkylating agent can be derived from a reformate, pyrolysis gasoline or coker naphtha.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.