Patent · US Expired

Method of manufacturing methylidene-group-containing .alpha.,.omega.-unsaturated oligomers from .alpha.,.omega.-diolefins in the presence of organoaluminum compounds as catalysts

US5306856A · kind A · utility

11Cited by
10References
9Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 12, 1992
Grant dateApr 26, 1994
Priority date
Expiry dateJun 12, 2012

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C2531/14
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A method of manufacturing methylidene-group-containing .alpha.,.omega.-unsaturated oligomers from .alpha.,.omega.-diolefins in the presence of a catalytic amount of organoaluminum compounds, wherein the .alpha.,.omega.-diolefins are reacted in the liquid phase, at 150.degree.-350.degree. C., and the organoaluminum compounds have formula AlX.sub.3 or AlX.sub.2 H, where X represents an aliphatic, alicyclic, or aromatic hydrocarbon group with 1-30 C atoms. The higher molecular weight hydrocarbons manufactured according to this method are substantially linear oligomers which contain reactive double bonds.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.