Patent · US Expired

Surface passification of a group IVB metal sponge regulus

US5308378A · kind A · utility

4Cited by
6References
3Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 24, 1993
Grant dateMay 3, 1994
Priority date
Expiry dateFeb 24, 2013

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC22B34/14
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

A zirconium sponge regulus from a Kroll reduction process is contaminated with zirconium chlorides, unreacted magnesium and magnesium chloride. The sponge regulus is vacuum distilled at a temperature of at least 800.degree. C. and then cooled. Before opening the distillation vessel and exposing the sponge regulus to the atmosphere, the vessel is backfilled with a gas comprising 25% to 75%, by volume, carbon dioxide, carbon monoxide or mixtures thereof, with the balance an inert gas and impurities associated therewith. The sponge regulus is less susceptible to fires when exposed to the air or crushing in downstream processing, and the metal surfaces of the sponge regulus are passivated whereby the overall contamination of the sponge is significantly reduced.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.