Patent · US Expired

Liquid methylene diphenyl diisocyanate

US5319054A · kind A · utility

29Cited by
10References
6Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 2, 1993
Grant dateJun 7, 1994
Priority date
Expiry dateSep 2, 2013

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C275/60
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The present invention relates to a process for the production of a allophanate-modified MDI which is a storage stable liquid at 25.degree. C. comprising (A) reacting (i) one equivalent of a diisocyanate and (ii) one equivalent of an aliphatic alcohol containing from 1 to about 36 carbon atoms or aromatic alcohol containing from 6 to 18 carbon atoms to form a diurethane of the diisocyanate, (B) reacting the product of (A) with 4,4'-diphenylmethane diisocyanate containing from 2 to 60% by weight 2,4'-MDI and less than 6% by weight of the 2,2'-MDI, in an amount sufficient to provide an allophanate having an isocyanate group content of about 12.0 to 30.0%.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.