Patent · US Expired

Homogeneous catalytic hydrodechlorination of chlorocarbons

US5326914A · kind A · utility

7Cited by
2References
8Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMay 27, 1993
Grant dateJul 5, 1994
Priority date
Expiry dateMay 27, 2013

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C17/23
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

This invention relates to a liquid phase process for the preparation of R.sub.f CHXY by the homogeneous catalytic hydrodechlorination of R.sub.f CClXY wherein X and Y are independently H, F, Cl or R.sub.f ' provided X and Y are not both Cl, R.sub.f and R.sub.f ' are independently F, CF.sub.3, (CF.sub.2).sub.n Cl or (CF.sub.2).sub.n CF.sub.3, and n is 1-4, by reacting the R.sub.f CClXY with hydrogen while in solution with a Periodic Table Group 6-10 metal complex catalyst which contains tertiary Periodic Table Group 15 ligands without added base.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.