Process for preparing 2,5-diphenylterephthalic acid by oxidation
US5334754A · kind A · utility
6Cited by
9References
5Claims
0Family size
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Key dates
| Filing date | Aug 14, 1992 |
| Grant date | Aug 2, 1994 |
| Priority date | — |
| Expiry date | Aug 14, 2012 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/582
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Provided is a process for preparing 2,5-diphenylterephthalic acid, which is useful in preparing certain polyesters, especially liquid-crystalline polyesters. In this process, p-xylene is di-alkylated with cyclohexene to provide 2,5-dicyclo-hexyl-p-xylene, which is in turn dehydrogenated to provide 2,5-diphenylxylene. 2,5-Diphenylxylene is then oxidized to provide 2,5-diphenylterephthalic acid by utilization of a cobaltous/manganous/bromide oxidation system.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.