Ammoxidation of saturated hydrocarbons
US5336804A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Feb 8, 1993 |
| Grant date | Aug 9, 1994 |
| Priority date | — |
| Expiry date | Feb 8, 2013 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/52
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The alkanes, e.g., propane, are ammoxidized into admixtures containing .alpha.,.beta.-unsaturated nitriles, e.g., admixture of acrylonitrile and propylene, by reacting such alkane with ammonia and oxygen, in vapor phase, in the presence of a catalytically effective amount of a solid catalyst, at least one active catalytic phase of which having the empirical formula (I): EQU VSb.sub.a Bi.sub.b O.sub.x (I) optionally also containing iron and/or gallium and/or indium, in which a is a whole or fractional number equal to or greater than 1, b is a whole or fractional number equal to or greater than 0.01, and x is a whole or fractional number provided by the oxidation number of the other elements of the at least one active catalytic phase.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.