Patent · US Expired

Method for detection of chemicals by reversible quenching of silicon photoluminescence

US5338415A · kind A · utility

26Cited by
5References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 22, 1992
Grant dateAug 16, 1994
Priority date
Expiry dateJun 22, 2012

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG01N2021/6432
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

An n-type silicon (Si) wafer is galvanostatically etched in a hydrofluoric acid (HF)-containing solution while being illuminated with a 300 watt tungsten light source to form porous silicon with luminescent properties. Photoluminescence of the porous silicon is monitored using a short wavelength visible or ultraviolet light source and a monochromator/CCD detector assembly. Upon exposure to organic solvents, the photoluminescence is quenched. Within seconds of removal of the solvent, the original intensity is recovered and further exposure of the porous silicon to organic solvents will again result in quenching of the luminescence.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.