Process for making graft propylene polymers
US5344886A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | May 14, 1993 |
| Grant date | Sep 6, 1994 |
| Priority date | — |
| Expiry date | May 14, 2013 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F255/02
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A process for making a graft propylene copolymer in which a propylene polymer, selected from the group consisting of propylene homopolymers and propylene copolymers, is contacted with a polymerizable, unsaturated carboxylic acid or acid derivative in the presence of a coagent, said coagent selected from the group consisting of a first compound having the structural formula ##STR1## where R is a hydrocarbyl or a radical containing at least one atom of oxygen, sulfur, nitrogen, phosphorus or silicon; R.sup.1 is hydrogen or C.sub.1 -C.sub.12 alkyl or aryl; and x is an integer of 1 to 4, and a second compound having the structural formula ##STR2## where R' is a hydrocarbyl or a radical containing at least one atom of oxygen, sulfur, nitrogen, phosphorus or silicon; R.sup.2 is hydrogen or C.sub.1 -C.sub.1 2 alkyl or aryl; and y is an integer of 2 to 4, and a free radical generating compound. This contact occurs at a temperature above both the melting point of the propylene polymer and the decomposition temperature of the free radical generating compound.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.