Patent · US Expired

Process for the production of a tertiary alkyl ether comprising a fractionation section

US5364975A · kind A · utility

2Cited by
4References
20Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 5, 1993
Grant dateNov 15, 1994
Priority date
Expiry dateMay 5, 2013

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C41/06
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process for the preparation of a tertiary alkyl ether, in particular methyl tert. amyl ether (MTAE), is described which comprises reacting, in a reaction section, a charge constituted by a mixture of C.sub.5 hydrocarbons, including reactive isopentenes, with an aliphatic monoalcohol in excess, such as methanol, ethanol, propanol or isopropanol, and collecting in the bottom of a fractionation section the corresponding pure tert. alkyl ether. The head effluent, after condensation, is subdivided into a liquid reflux and a distillate. The process is further characterized by providing a finishing reactor for the reflux, or for the reflux + distillate effluent prior to the subdivision thereof, or two finishing reactors are provided, one for the reflux and the other for the distillate, along with the possibility of injecting aliphatic monoalcohol upstream of each finishing reactor.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.