Method for selectively removing antimony and bismuth from sulphuric acid solutions
US5366715A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Oct 19, 1993 |
| Grant date | Nov 22, 1994 |
| Priority date | — |
| Expiry date | Oct 19, 2013 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S210/912
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
The present invention is concerned with a method for selectively removing antimony and bismuth from an impure sulphuric acid solution containing at least 50 g/L of acid and some concentration of ferric ion (for example copper refinery electrolyte), is disclosed. The method involves contacting the impure solution with a sufficient quantity of finely divided metallic copper so as to prereduce all ferric ion present in the solution to the ferrous oxidation state. The prereduced solution is then contacted with a chelating resin. The method avoids the deleterious loading of ferric iron onto the ion exchange resin and prevents the return of excessive amounts of chloride ion with the purified electrolyte.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.