Adhesive compositions containing radial block copolymers with butadiene endblock and articles produced therefrom
US5372870A · kind A · utility
Assignees
Inventors
Key dates
| Filing date | Dec 17, 1993 |
| Grant date | Dec 13, 1994 |
| Priority date | — |
| Expiry date | Dec 17, 2013 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T442/678
- WIPO fieldMedical technology
- WIPO sectorInstruments
Abstract
Radial block copolymers characterized by the formulas: (1) (pS-pI).sub.n X and (2) (pS-pI-pB).sub.n X where pS is polystyrene, pI is polyisoprene, pB is butadiene, X is a residue of a multifunctional coupling agent used in the production of the radial block copolymer, and n is a number greater than 2 representative of the number of branches appended to X; hot-melt adhesive compositions constituted of said radial block copolymers, and articles of manufacture produced therefrom. These copolymers possess blocks of high average molecular weight polystyrene (10,000 to 25,000) and an overall average molecular weight (90,000 to 380,000) such that when blended in requisite proportions with a compatible tackifier resin, preferably also a secondary tackifying resin or plasticizing oil, and stabilizer, superior hot-melt adhesive compositions can be formed. The hot-melt adhesive compositions possess, inter alia, superior heat resistance, superior static time to failure with low viscosity, good peel adhesion, good tack, and high ability to bond to a polyethylene or polypropylene substrate at temperatures below that which may damage the substrate.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.