Production of dialkyl carbonates using copper catalysts
US5387708A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Dec 10, 1993 |
| Grant date | Feb 7, 1995 |
| Priority date | — |
| Expiry date | Dec 10, 2013 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/584
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A process for the production of dialkyl carbonates, such as dimethyl carbonate. In one aspect, the process involves contacting under reaction conditions an alkanol, such as methanol, with carbon monoxide and oxygen in the vapor phase and in the presence of a catalyst containing (1) a copper halide, a copper oxyhalide, or a copper carboxylate halide, (2) a quaternary ammonium salt, and (3) a support component. The catalyst achieves high selectivity and productivity to dialkyl carbonates. In a second aspect, the addition of a chlorocarbon catalyst regenerator to the alkanol feed increases catalyst stability and lifetime and increases the selectivity and/or productivity to dialkyl carbonates.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.