Process for the production of a multicoat coating, aqueous coating compositions, water-thinnable polyacrylate resins and process for the production of water-thinnable polyacrylate resins

US5393570A · kind A · utility

Assignee

• Basf Lacke & Farben Aktiengesellschaft · DE

Inventors

• Stephan Schwarte · Münster, DE
• Manfred Dangschat · Drensteinfurt, DE
• Manfred Reimann · Drensteinfurt, DE
• Carlos Westermann · Munster, DE

Key dates

• Filing date: Nov 24, 1992
• Grant date: Feb 28, 1995
• Expiry date: Nov 24, 2012

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C09D151/003
• WIPO field: Surface technology, coating
• WIPO sector: Chemistry

Abstract

The invention relates to a process for the production of a multicoat coating in which an aqueous transparent topcoat composition containing a polyacrylate resin as binder is employed. The polyacrylate resin can be obtained by adding, either successively or alternately in part amounts, a mixture of a carboxyl-containing ethylenically unsaturated monomer (a1) and a monomer (a2) free from carboxyl groups and a mixture (b) consisting of (meth)acrylic acid esters which are free from carboxyl groups, of hydroxyl-containing ethylenically unsaturated monomers and, if appropriate, of other ethylenically unsaturated monomers to an organic solvent and carrying out a polymerization in the presence of a radical-forming initiator and, at the end of the polymerization, neutralizing the resultant polyacrylate resin and dispersing it in water. The type and amount of (a1), (a2) and (b) are chosen so that the polyacrylate resin has a hydroxyl value of 40 to 200, an acid value of 20 to 100 and a glass transition temperature (T.sub.G) of -40.degree. C. to +60.degree. C.