Processes for removing, separating and concentrating lead, thallium, alkali metals, alkaline earth metals from concentrated matrices using macrocyclic polyether cryptand ligands bonded to inorganic supports
US5393892A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | May 7, 1993 |
| Grant date | Feb 28, 1995 |
| Priority date | — |
| Expiry date | May 7, 2013 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P10/20
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
A method for the removal, separation, and concentration of alkali metal, alkaline earth metal, Pb and/or Tl cations from a source solution which may contain larger concentrations of other ions comprises bringing the source solution into contact with a compound comprising an oxygen donor macrocycle-containing ligand covalently bonded through an organic spacer silicon grouping to a solid inorganic support. The ligand portion(s) of the compound has affinity for alkali metal, alkaline earth metal, Pb and/or Tl thereby removing them from the source solution. The alkali metal, alkaline earth metal, Pb and/or Tl cations are then removed from the compound through contact with a much smaller volume of a receiving solution in which these cations are either soluble or which has greater affinity for such cations than does the oxygen donor macrocyclic ligand thereby quantitatively stripping the complexed cations from the ligand and recovering them in concentrated form in said receiving solution. The concentrated cations thus removed may be further separated and recovered by known methods. The process is useful in the removal of alkali metal, alkaline earth metal, Pb and Tl cations from a variet…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.