Pressure sensitive adhesive composition which is water dispersible under alkaline pH conditions
US5397614A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 16, 1993 |
| Grant date | Mar 14, 1995 |
| Priority date | — |
| Expiry date | Jul 16, 2013 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T442/2754
- WIPO fieldBasic materials chemistry
- WIPO sectorChemistry
Abstract
A pressure sensitive adhesive which is dispersible at an alkaline pH but not at an acidic or a neutral pH is disclosed. The adhesive is essentially free from plasticizers (i.e., it contains less than 0.1 part of plasticizer per part of polymer). The polymer is formed from A, B and C monomers. The A monomer is hydrophobic and is an acrylic or methacrylic ester of a non-tertiary C.sub.2 -C.sub.14 alcohol. It comprises from 50 to 80 weight % of the polymer. The B monomer contains .beta.-carboxyethyl acrylate (BCEA) or a salt thereof or a mixture of BCEA or a salt thereof with a vinyl carboxylic acid or a salt thereof. The polymer contains from 10 to 30 weight % of B monomer. The acid groups of the polymer have been neutralized with from 0.5 to 2 equivalents of an alkali metal hydroxide. The C monomer is an X--Y--Z macromer. X is copolymerizable with the A and B monomers. Y is a divalent linking group. Z is a water dispersible group that contains at least two units which are essentially unreactive under free radical conditions used to form the polymer. C comprises from 10 to 30 weight % of the polymer.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.